When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CF3C(O)F_IUPAC(2008)_238K_200-295nm(rec).txt |
| NAME: | trifluoroacetyl fluoride |
| FORMULA: | CF3C(O)F |
| AUTHOR(YEAR): | IUPAC(2008) |
| T: | 238K |
| λ: | 200-295nm(rec) |
| BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and T.J. Wallington, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species",
Atmos. Chem. Phys. 8, 4141-4496 (2008);
DOI: 10.5194/acp-8-4141-2008
|
| COMMENTS: | IUPAC(2008) recommendation: Mean of the data of O.V. Rattigan, O. Wild, R.L. Jones, and R.A. Cox, "Temperature-dependent absorption cross-sections of CF3COCl, CF3COF, CH3COF, CCl3CHO and CF3COOH," J. Photochem. Photobiol. A: Chem. 73, 1-9 (1993); DOI: 10.1016/1010-6030(93)80026-6
, and R. Meller, D. Boglu, and G.K. Moortgat, "Absorption cross sections and photolysis studies of halogenated carbonyl compounds. Photooxidation studies on CF3-containing CFC-substitutes.," presented at the Kinetics and Mechanisms for the Reactions of Halogenated Organic Compounds in the Troposphere. STEP-HALOCSIDE/AFEAS Workshop, Dublin, Ireland, 1993. Parameterization of the temperature dependence by ln σ(T) = ln σ(293 K) + B × (T - 293) with the temperature coefficients ------------------
λ 103 B
(nm) (K-1)
------------------
200 -0.21
205 -0.16
210 -0.31
215 0.03
220 0.40
225 0.83
230 1.23
235 1.87
240 2.99
245 4.91
250 6.60
255 9.36
260 12.40
265 18.77
270 26.36
275 34.73
280 23.32
285 25.21 |
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